畜禽环境中抗生素的去除及其风险评估

抗生素作为饲料添加剂广泛应用于畜禽养殖业,造成养殖环境抗生素大量蓄积,尤其是在畜禽粪便中,长期的积累不仅污染养殖场内土壤环境,残留的抗生素还会随畜禽粪便进入周边水体及农田环境,威胁农作物及人体健康。目前,国内相关研究主要集中在抗生素的降解工艺及降解规律方面,而对其去除效率的影响因素及风险评价研究相对较少。笔者综述了国内外抗生素的降解转化及去除方式等的研究进展,并概述了抗生素在畜禽环境中的生态风险评估的研究现状,为抗生素的高效去除、风险预估及畜禽粪便资源化安全利用提供理论基础和技术支撑。     

Environmental forensic investigation of the air pollution from a cement manufacturing unit

Abstract

Cement manufacturing is a process that results in the emission of significant quantities of suspended particulate matter (SPM) to the ambient air. An environmental forensic investigation was carried out in the surroundings of a major cement manufacturing unit at a place called Coimbatore in the southern Indian state of Tamil Nadu. The investigation was carried out to identify the contribution of the cement manufacturing unit to the SPM concentration of the surrounding air environment. The sampling points’ selection and sample collection were done following the principles outlined in the INTERPOL Manual for Pollution Crime Forensic Investigation. On-site monitoring of the air samples was carried out using Mini Laser Aerosol Spectrometer (GRIMM, Mini-LAS Model 11R). The instrument was capable of measuring particles ranging from 0.25 to 32 µm and classifying them into 31 size channels. The test results at majority of the monitoring locations were well above the limits specified in the National Ambient Air Quality Standards of India. Microscopic studies of the dust samples were carried out for surface texture and particle shape. The spatial distribution of particles was analysed using geographic information system (GIS) for the visual identification of the extent of the pollution by keeping the cement factory as the focal point. The results from the GIS and microscopic analysis established the role of the cement factory in the particulate matter pollution of its surroundings, specifically in the areas North-West of the factory. The successfully adopted procedure can serve as a guideline for the environmental forensic investigation of similar pollution incidences.     

铁路沿线可燃重气储罐最小隔离区域划分探讨*

为保护铁路线，以某化工厂距离高铁路线最近的丙烯球罐为例，提出丙烯球罐泄漏最小隔离区域划分方法以及2种保护高铁线路方案，利用重气扩散模型和定量风险评价（QRA）软件分别进行丙烯扩散模拟、爆炸模拟，并进行危险与可操作性分析（HAZOP）和保护层分析（LOPA）。结果表明:球罐发生泄漏及火灾爆炸等事故，会给附近铁路线带来严重破坏；丙烯泄漏或球罐因周围其他设备设施或可燃物质着火而温度升高时，保护措施不足；隧道的安全可靠性要高于仅设1道防爆墙，隧道长度需覆盖最小隔离区域的可及范围，在扩散区域内也需设立普通挡墙，在极度危险情况下，需要实施高铁停开等保护措施。     

四川省眉山市“三线一单”编制案例分析

通过四川省眉山市“三线一单”编制试点工作的开展,探索出适合四川省情、尺度得当、具有可操作性的环境管控单元划分方法和适用技术方法以及生态环境准入清单制定原则,为全省“三线一单”编制工作的顺利推进起到了示范和引领作用。     

交联剂TAIC反应风险评估分析

利用全自动反应量热仪和绝热加速量热仪等相关实验仪器检测出TAIC(三烯丙基异氰尿酸酯)合成反应的反应热、比热容及热稳定性等数据,依据绝热温升、工艺温度、技术最高温度、最大反应速率到达时间及失控体系可能达到的最高温度这5个温度参数按照评估标准从分解热、严重度、可能性、矩阵、工艺危险度这5个方面分别进行评估。通过对热参数及实验过程进行分析提出降低工艺危险等级的工艺优化方法。根据最终评估结果对TAIC生产装置的安全性进行评价,提出相应的整改措施及建议。     

脆弱性基本原理与控制方法

本文从社会进步导致自反性危机出发,通过对风险承载体脆弱性构成要素暴露度、敏感度、适应度的分析,提出了三特征要素递次演化的模型;并根据脆弱性的递次演化的特点,提出了对脆弱性的辨识和递次管控的基本思路;最后,依据对地铁运行安全管理脆弱性的研究,进行脆弱性管理的实证分析。     

氢安全研究现状及面临的挑战

氢能具有储运便捷、来源多样、洁净环保等突出优点,许多国家把发展氢能作为重要的能源战略。氢安全是氢能大规模商业化应用的重要保障。在分析国内外氢安全领域近年来最新研究进展的基础上,依次从氢泄漏与扩散、氢燃烧与爆炸、氢与金属材料相容性及氢风险评价等方面,系统总结了国内外氢安全研究面临的挑战,并对我国氢安全的发展提出了建议。     

Utilization of MSWI fly ash as partial cement or sand substitute with focus on cementing efficiency and health risk assessment

• Washed MSWI fly ash was used as partial cement or sand substitute. • Sand replacing is beneficial for strength, while cement replacement reduces strength. • Cementing efficiency factor and mortar pore structure explain the strength results. • Health risk assessment was conducted for MSWI fly ash blended cement mortar. • CR and HI contributed by different exposures and heavy metals were analyzed. The strength of cement substituted mortar decreases with the increase in fly ash amount, whereas the strength increases when the fly ash is blended as sand substitute. A mortar with highest strength (compressive strength= 30.2 Mpa; flexural strength= 7.0 Mpa) was obtained when the sand replacement ratio was 0.75%. The k value (cementing efficiency) of fly ash varied between 0.36 and 0.15 for the fly ash fraction in binder between 5% and 25%. The k values of fly ash used for sand replacement were all significantly above that used for cement substitution. The macropores assigned to the gaps between particles decreased when the fly ash was used as sand replacement, providing an explanation for the strength enhancement. The waste-extraction procedure (toxicity-sulphuric acid and nitric acid method (HJ/T 299-2007)) was used to evaluate metal leaching, indicating the reuse possibility of fly ash blended mortar. For the mortar with the mass ratio of fly ash to binder of 0.5%, the carcinogenic risks (CR) and non-carcinogenic hazard quotient (HQ) in sensitive scenario for blended mortar utilization were 9.66 × 10^-7 and 0.06, respectively; these results were both lower than the threshold values, showing an acceptable health risk. The CR (9.89 × 10^-5) and HQ (3.89) of the non-sensitive scenario for fly ash treatment exceeded the acceptable threshold values, indicating health risks to onsite workers. The main contributor to the carcinogenic and non-carcinogenic risk is Cr and Cd, respectively. The CR and HQ from inhalation was the main route of heavy metal exposure.     

我国高速公路周边土壤重金属污染现状及研究进展

以我国高速公路周边土壤重金属为研究对象，综述了我国高速公路周边土壤重金属污染特征、影响因素、来源、环境风险及其研究进展。高速公路周边土壤主要受Pb、Cd、Cr、Cu、Zn等重金属污染，主要呈现指数分布、偏态分布和两者混合分布等特点，并且受到土地利用、风向、地形、车流量等多种因素的综合影响。土壤重金属的来源除了受成土母质等自然因素影响以外，公路交通和周边工农业活动也会对其来源产生较大影响。传统的土壤重金属评价方法主要采用单因子指数法、地累积指数法、生态风险评价法等对重金属的污染等级和环境风险进行评价。未来的研究应将重金属形态分析、空间和地统计分析、重金属稳定同位素示踪和源解析模型以及预测模型等多种手段相结合，开展高速公路周边土壤重金属的污染特征、时空分布、来源及预测预警研究等，为我国高速公路沿线工农业生产布局及其土壤重金属污染防控提供科学依据和决策支撑。     

国家重点生态功能区县域环境监测质量评价方法及应用示范

以国家重点生态功能区县域环境监测质量评价为目标,综合应用德尔菲法、层次分析法和模糊综合评价法,构建了国家重点生态功能区县域环境监测质量评价方法,并确定了评价因子、权重系数、计算方法。该方法评价指标共分为三层:第一层为目标层,即国家重点生态功能区县域环境监测质量;第二层为准则层,包括人员及资质、现场监测、实验室管理、报告编制及数据上报;第三层为方案层,包括人员操作、持证上岗、资质认定、人员培训、水质布点采样流转情况、空气自动站运维情况、现场质控实施情况、实验室环境条件、样品试剂的保存与管理、仪器检定与校准、实验室质量控制实施情况、数据填报软件运行情况、监测报告规范性等13个评价要素。经矩阵一致性检验确定了各评价要素的权重,将该权重与各要素得分运算后得到县域环境监测质量评价结果。在此基础上,选取广东、山西、陕西、四川和青海等5个省份的15个国家重点生态功能区县域作为典型区开展了实地调研,并应用评价体系对其进行了监测质量等级评价。结果表明,15个典型县域中,环境监测质量等级为优的县域占13.3%,一般、较差的县域分别占66.7%、20%。县域环境监测承担单位在资质、报告编制及数据上报方面表现较好,在现场监测、人员操作方面问题突出,在实验室管理方面有待提升。